- Scored the winning penalty kick against Argentina National Football Team at the 2015 Copa América final (first title for Chile in its history).
- Forward for C.D. Cobreloa (2005-06), Colo-Colo (2006-07), River Plate (Argentina, 2007-08), Udinese Calcio (Italy, 2008-2011), FC Barcelona (Spain, 2011-2014), Arsenal F.C. (England, 2014-2018), Manchester United F.C. (England, 2018-19), Inter Milan (Italy, 2019-2022, 2023-) and Olympique de Marseille (France, 2022-23).
- Honours with Colo-Colo: Chilean Primera División (2006 Clausura, 2007 Apertura). Honours with River Plate: Argentine Primera División (2008 Clausura). Honours with FC Barcelona: Spanish Super Cup (2011, 2013); UEFA Super Cup (2011); FIFA Club World Cup (2011); Copa del Rey (2012); La Liga (2013). Honours with Arsenal F.C.: Community Shield (2014, 2015, 2017); FA Cup (2015, 2017). Honours with Inter Milan: Serie A (2021); Supercoppa Italiana (2021); Coppa Italia (2022).
- Member of the Chilean youth team who won 3rd place at the 2007 FIFA U20 World Cup.
- Was romantically involved with Faloon Larraguibel, Ariela Medeiros, Carla Ochoa, Dani Urrizola, Mariana Marino, Roxana Muñoz, Valentina Roth, Michelle Carvalho, Melina Figueroa, Francisca Undurraga and Anna Modler.
- Ex-girlfriends: Laia Grassi (2013-2014) and Mayte Rodríguez (2017-2018).
- Won two Copa América (2015 and 2016) and runner-up at the FIFA Confederations Cup (2017) with Chile National Team.
- International with Chile National Football Team since 2006. Member of the Copa América 2011, 2015, 2016, 2019, Confederations Cup 2017, and the South Africa '10 and Brazil '14 squads.
- Has a song about his called "El niño maravilla" by the cumbia band Tomo Como Rey.
- Won the FSF Player of the Year Award in 2015.
- Named in the 2014-15 PFA Team of the Year.
- Golden Ball at the 2016 Copa América.
- Chile National Football Team's all-time top goal scorer.
- Silver Ball at the 2017 FIFA Confederations Cup.
- Scored goals for Arsenal F.C. during the finals matches of FA Cup 2015 and 2017.
- Finished 10th at the FIFA Ballon d'Or 2015 (2016).
- Named the Arsenal Player of the Season two times in 2014/15 and 2016/17.
- Most assists of the UEFA Champions League (2016).
- Nominee at The Best FIFA Player twice (2016 and 2017).
- Man of the Match of the 2017 FA Cup Final and the 2021 Supercoppa Italiana.
- Has been sponsored by Gillette, Huawei and Pepsi.
- 2018: Release JJO clothing collection in Chile.
- Debut as film actor on Mi Amigo Alexis (2019).
- Scored the 2:1 goal in the extra time for Inter Milan against Juventus F.C. during the final match of Supercoppa Italiana 2021.
- He equaled the Hernan Crespo record on the FIFA World Cup qualification (CONMEBOL) list of the all-time top goalscorers with 19 goals.
- Named the Marseille Player of the Season 2022/23.
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